Monday, February 4, 2019

Tuning of the exchange interaction and the Curie temperature by mixed crystal formation of the bridging anionic ligands

Chem. Commun., 2019, Accepted Manuscript
DOI: 10.1039/C8CC09392J, Communication
Tristan Neumann, Michał Rams, Zbigniew Tomkowicz, Inke Jess, Christian Nather
Mixed crystals with the composition [Co(NCS)x (NCSe)2−x(pyridine)2]n were prepared from solution and by annealing of Co(NCS)x(NCSe)2−x(pyridine)4. With increasing selenocyanate content, an increase of the magnetic exchange constant and of the...
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