Monday, February 4, 2019

Molecular Doping: Accessing the First Carborane-substituted 1,2,3-Triphospholanide via Insertion of P− into a P−P bond

Chem. Commun., 2019, Accepted Manuscript
DOI: 10.1039/C9CC00205G, Communication
Evamarie Hey-Hawkins, Peter Coburger, Hansjoerg Gruetzmacher
Insertion of a P− anion into a P−P bond yielding the first carborane-substituted 1,2,3-triphospholanide 1 was achieved by treating a carborane-substitued 1,2-diphosphetane with sodium phosphaethynolate. The triphospholanide 1 can serve...
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