Octahedron-shaped three-shell Ln14-substituted polyoxotungstogermanates encapsulating a W4O15 cluster: luminescence and frequency dependent magnetic properties

Chem. Commun., 2019, Accepted Manuscript
DOI: 10.1039/C9CC00073A, Communication

Yong-Jiang Wang, Shi-Yu Wu, Yan-Qiong Sun, Xin-Xiong Li, Shou-Tian Zheng
A series of new Ln14-substituted polyoxometalates H27Na16[(Ln14(H2O)W4(OH)O14)(WO4)4(GeW10O38)6]∙nH2O ( n ≈ 86 ) (1-Ln, Ln=Eu, Gd, Tb, Dy, Ho, Er), which contain 14 Ln3+ and 6 {α(1,5)-[GeW10O38]12-} units, have been synthesized...
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