Wednesday, January 30, 2019

Halogen Bonding Effects on the Outcome of Reactions at Metal Centres

Chem. Commun., 2019, Accepted Manuscript
DOI: 10.1039/C8CC08884E, Communication
Lucas Carreras, Jordi Benet-Buchholz, Antonio Franconetti, Antonio Frontera, Piet W.N.M. van Leeuwen, Anton Vidal-Ferran
Key findings regarding the effects of ligand preorganisation via halogen bonding on the outcome of reactions at rhodium are reported. An unprecedented halogen bonding-mediated oxidative addition of CAr-I bonds to...
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The Guardian: Green Car Maker Tesla Just Laid Off a Quality Control Department

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Guest essay by Eric Worrall h/t Breitbart – According to The Guardian, Tesla's recent layoffs include an entire quality control department. 'How do they expect to run without us?' Tesla accused of axing key staff to cut costs Electric car firm slashed 7% of workforce this month and ex-employees say more experienced staff were targeted…

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Inhibitor structure-guided design and synthesis of near-infrared fluorescent probe for Monoamine Oxidase A (MAO-A) and its application in living cells and in vivo

Chem. Commun., 2019, Accepted Manuscript
DOI: 10.1039/C8CC10084E, Communication
zhengmin yang, wenxiu li, Hua Chen, qingyuan mo, jun li, Shulin Zhao, Cheng Hou, Jiang-ke Qin, Guifa SU
A series of near-infrared fluorescent probes based on inhibitor (clorgyline) structure-guided were designed and synthesized for the specific detection of MAO-A in cells and in vivo. Moreover, we have successfully...
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Nickel-Catalyzed Alkyl-Alkyl Cross-Coupling Reactions of Non-activated Secondary Alkyl Bromides with Aldehydes as Alkyl Carbanion Equivalents

Chem. Commun., 2019, Accepted Manuscript
DOI: 10.1039/C9CC00307J, Communication
Junliang Zhang, Chenhao Zhu
A novel nickel-catalyzed alkyl-alkyl cross coupling of unactivated secondary alkyl bromides with aldehydes via hydrazone intermediates has been developed. Aldehyde as an alkyl carbanion equivalent replaces traditional organometallic reagents. This...
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Midweek Unthreaded

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Hollywood Melts After Trump Mocks Global Warming: ‘Inhumane Unethical Pathetic Imbecile’

http://bit.ly/2sVspMw Hollywood Melts After Trump Mocks Global Warming: 'Inhumane Unethical Pathetic Imbecile' 30 Jan 20194,503 2:15 Hollywood celebrities got seriously heated Tuesday after President Donald Trump mocked global warming amid record low temperatures across the county. "In the beautiful Midwest, windchill temperatures are reaching minus 60 degrees, the coldest ever recorded. In coming days, expected [...]

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Fascinating animation showing the #polarvortex slamming the USA

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From NASA Goddard: Desperately cold weather is now gripping the Midwest and Northern Plains of the United States, as well as interior Canada. The culprit is a familiar one: the polar vortex. A large area of low pressure and extremely cold air usually swirls over the Arctic, with strong counter-clockwise winds that trap the cold…

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Ocasio-Cortez, Markey to unveil Green New Deal bill

http://bit.ly/2UsEdS8 Ocasio-Cortez, Markey to unveil Green New Deal bill Sen. Ed Markey and Rep. Alexandria Ocasio-Cortez. Photos: Scott Eisen via Getty Images; Tom Williams/CQ Roll Call Rep. Alexandria Ocasio-Cortez (D-N.Y.) and Sen. Ed Markey (D-Mass.) are set to unveil legislation laying out a "Green New Deal" as soon as next week, Axios has learned. Driving [...]

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House Democrats Just Told the Pentagon to Redo Its Climate Change Report – Demand new report ‘rigorously confronts the realities of our warming planet’

http://bit.ly/2sXTvCF BY DAN SPINELLI Earlier this month, the Pentagon released a landmark report that identified the 79 American military installations most vulnerable to the "effects of a changing climate." The 22-page filing frankly acknowledged the security implications of climate change—in dramatic contrast with President Trump's very public global warming skepticism—but Democrats roundly criticized its failure to include several details requested by Congress, including specific [...]

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[ASAP] Synthesis, Structures, and Magnetic Properties of Two Coordination Assemblies of Mn(III) Single Molecule Magnets Bridged via Photochromic Diarylethene Ligands

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Inorganic Chemistry
DOI: 10.1021/acs.inorgchem.8b02578
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AP: Parts of Midwest Colder Than Antarctica During Deep Freeze

http://bit.ly/2MHhRd7 BISMARCK, N.D. — The deadly deep freeze enveloping the Midwest sent temperatures plunging Wednesday to rival some of the most frigid spots in the world, triggering widespread closures of schools and businesses, and the canceling of more than 1,600 flights to and from Chicago's airports. The U.S. Postal Service even took the rare step [...]

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Listen: Morano on radio discusses how ‘warming’ does not record cold/snow – Jeff Poor Show

The Jeff Poor Show (1-30-19) Climate Depot's Marc Morano joins the show to discuss his new book and common hoax's of climate change Related Links:  Blaming cold on 'warming' is 'pseudo-scientific scam' – Scientist retires…then declares 'I am a skeptic' – The 'sea of plastic is a fiction' – Climate Depot News Round-Up UN IPCC's [...]

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Hell has frozen over – no, really!

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There's a town called "Hell", in Michigan. That's the sign from the city limits. Today, there was this bit of meteorological info on Twitter: It's -7 degrees in Hell, Michigan, right now, with a wind chill of -28. You know what that means people… Hell has literally frozen over. — Derek Wallbank (@dwallbank) January 30,…

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UN IPCC’s Kevin Trenberth rebukes fellow warmists on polar vortex claims! ‘Frankly, it is a stretch to make that link…this is in realm of weather — Not climate’ …

http://bit.ly/2MLdAWc 'WE'VE BECOME DUMBER': MEDIA RUSHES TO TIE RECORD-BREAKING COLD ON GLOBAL WARMING By MICHAEL BASTASCH A "polar vortex" event is breaking record-low temperature readings across the Great Plains and Midwest, and many in the media are rushing to blame the deep freeze on global warming. The New York Times, for example, filled the top of its [...]

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Michael Bloomberg blames icy Midwestern cold front on ‘global warming’ – Scientists reject claim

http://bit.ly/2RsyKc1 By Valerie Richardson – The Washington Times – Updated: 5:19 p.m. on Wednesday, January 30, 2019 Former New York City Mayor Michael Bloomberg blamed Wednesday the frigid cold temperatures sweeping the Midwest on global warming, arguing that climate change makes weather events more extreme. "The science is clear: Climate change makes extreme weather more frequent and more intense," [...]

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Fulfilling the Promise of Bears Ears



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Fulfilling the Promise of Bears Ears



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Extreme rainfall events are connected across the world


We're told there are patterns which 'appear to be created by Rossby waves – wiggles in fast-flowing currents of air high in the atmosphere, known as the jet streams.'

An analysis of satellite data has revealed global patterns of extreme rainfall, which could lead to better forecasts and more accurate climate models, reports Phys.org.

Extreme rainfall—defined as the top five percent of rainy days—often forms a pattern at the local level, for example tracking across Europe.

But new research, published today in Nature, reveals that there are also larger-scale global patterns to extreme rainfall events.

These patterns connect through the atmosphere rather than over land—for example, extreme rainfall in Europe can precede extreme rainfall in India by around five days, without extreme rain in the countries in between.

The research, led by a team at Imperial College London and the Potsdam Institute for Climate Impact Research in Germany, could help better predict when and where extreme rainfall events will occur around the world. The insights can be used to test and improve global climate models, leading to better predictions.

The study additionally provides a 'baseline' for climate change studies. By knowing how the atmosphere behaves to create patterns of extreme rainfall events, scientists will be able to gain new insights into changes that may be caused by global warming.

Lead author Dr. Niklas Boers, from Potsdam Institute for Climate Impact Research and the Grantham Institute—Climate Change and Environment at Imperial, said: "Uncovering this global pattern of connections in the data can improve weather and climate models.

This is especially true for the emerging picture of couplings between the tropics and the European and North American regions and their consequences for extreme rainfall.

"This finding could also help us understand the connections between different monsoon systems and extreme events within them. I hope that our results will, in the long term, help to predict extreme rainfall and associated flash floods and landslides in northeast Pakistan, north India and Nepal. There have been several such hazards in recent years, with devastating consequences in these regions, such as the 2010 Pakistan flood."

To find patterns in extreme rainfall events, the team developed a new method rooted in complex system theory to study high-resolution satellite data of rainfall.

Continued here.



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Climate Fish Tales

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What's Natural? Guest essay by Jim Steele   American folk lore is filled with stories of how Native Americans observed changes in wildlife and foretold future weather changes. I was fascinated by an 1800s story of Native Americans inhabiting regions around Marysville, California who had moved down into the river valleys during drought years. They then…

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[ASAP] Temperature- and Mn2+ Concentration-Dependent Emission Properties of Mn2+-Doped ZnSe Nanocrystals

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Journal of the American Chemical Society
DOI: 10.1021/jacs.8b08480
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[ASAP] Coupled X-ray Absorption/UV–vis Monitoring of Fast Oxidation Reactions Involving a Nonheme Iron–Oxo Complex

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Journal of the American Chemical Society
DOI: 10.1021/jacs.8b08687
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[ASAP] Two-Dimensional Hybrid Perovskite-Type Ferroelectric for Highly Polarization-Sensitive Shortwave Photodetection

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Journal of the American Chemical Society
DOI: 10.1021/jacs.8b12948
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[ASAP] Electron Paramagnetic Resonance Signature of Tetragonal Low Spin Iron(V)-Nitrido and -Oxo Complexes Derived from the Electronic Structure Analysis of Heme and Non-Heme Archetypes

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Journal of the American Chemical Society
DOI: 10.1021/jacs.8b11429
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[ASAP] Molecule Self-Assembly Synthesis of Porous Few-Layer Carbon Nitride for Highly Efficient Photoredox Catalysis

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Journal of the American Chemical Society
DOI: 10.1021/jacs.8b12428
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[ASAP] Catalysis through Dynamic Spacer Installation of Multivariate Functionalities in Metal–Organic Frameworks

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Journal of the American Chemical Society
DOI: 10.1021/jacs.8b12372
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[ASAP] Harnessing Alkylpyridinium Salts as Electrophiles in Deaminative Alkyl–Alkyl Cross-Couplings

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Journal of the American Chemical Society
DOI: 10.1021/jacs.9b00111
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[ASAP] Bifunctional Mononuclear Dysprosium Complexes: Single-Ion Magnet Behaviors and Antitumor Activities

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Inorganic Chemistry
DOI: 10.1021/acs.inorgchem.8b02250
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[ASAP] Forging Ru–Csp2 Bonds in Paddlewheel Complexes Using the Lithium–Halogen Exchange Reaction

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Inorganic Chemistry
DOI: 10.1021/acs.inorgchem.8b03216
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[ASAP] Supramolecular Aggregate of Cadmium(II)-Based One-Dimensional Coordination Polymer for Device Fabrication and Sensor Application

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Inorganic Chemistry
DOI: 10.1021/acs.inorgchem.8b03294
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A novel near-infrared fluorescent light-up probe for tumor imaging and drug-induced liver injury detection

Chem. Commun., 2019, Accepted Manuscript
DOI: 10.1039/C8CC10286D, Communication
xiaodong zeng, Ziyang Chen, Lin Tang, Han Yang, Nan Liu, Hui Zhou, Yang Li, junzhu Wu, Zixin Deng, Yi Yu, Hai Deng, Xuechuan Hong, Yuling Xiao
A novel near-infrared fluorescent light-up probe with a tumor-homing pentapeptide, CREKA (Cys-Arg-Glu-Lys-Ala), specifically binds to fibrin-fibronectin complexes was rationally designed and developed for biomedical imaging. Its superior practical applications of...
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[ASAP] Are Chalcogenide Perovskites an Emerging Class of Semiconductors for Optoelectronic Properties and Solar Cell?

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Chemistry of Materials
DOI: 10.1021/acs.chemmater.8b04178
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[ASAP] Role of Oleylamine Revisited: An Original Disproportionation Route to Monodispersed Cobalt and Nickel Nanocrystals

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Chemistry of Materials
DOI: 10.1021/acs.chemmater.8b04435
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[ASAP] Self-Propelled and Targeted Drug Delivery of Poly(aspartic acid)/Iron–Zinc Microrocket in the Stomach

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ACS Nano
DOI: 10.1021/acsnano.8b06773
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