Tuesday, February 26, 2019

How power-to-gas technology can be green and profitable

From the "you can wish in one hand…" dept Public Release: 26-Feb-2019 Economists map out economically viable path to renewables-based hydrogen production Technical University of Munich (TUM) Hydrogen production based on wind power can already be commercially viable today. Until now, it was generally assumed that this environmentally friendly power-to-gas technology could not be implemented…

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A Novel Reactive Turn-On Probe Capable of Selective Profiling and No-Wash Imaging of Bruton’s Tyrosine Kinase in Live Cells

Chem. Commun., 2019, Accepted Manuscript
DOI: 10.1039/C9CC01059A, Communication
Zhengqiu Li, Xin Wang, Ke Ding, Nan Ma, Rui Wu
Bruton's tyrosine kinase, an essential mediator of B cell receptor (BCR) signalling, has been validated as an effective therapeutic target in oncology. Development of chemical sensors capable of precise detection...
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The impact of fertilizers on the uptake of manganese in Cherry Belle radish plants: implications for human health

Abstract

Miracle-Gro Singles, Miracle-Gro Shake and Feed, and Vigoro fertilizers are associated with net loss/enhancement of Mn, up to an order of magnitude when referenced to controls in soil, radish vegetables, and radish leaves; Mn enhancements are a factor of 4 to 65 below the daily required intake for humans (2–5.5 mg/day). Manganese levels were measured by atomic absorption spectrometry (AAS). Control soil, radish vegetables, and radish leaves contained 65 μg/g to 146 μg/g (median = 108), 65 μg/g to 357 μg/g (median = 281), and 185 μg/g to 401 μg/g (median = 323) of Mn, correspondingly. Manganese uptake was ten times greater in radish leaves compared to radish vegetables and enhanced by a factor of 3 in soils. Edible radish leaves/vegetables contain 65 times less than human Mn daily requirements. This equates eating 140 lb/day of radish vegetables/leaves. The fertilizers have a minor impact on Mn accumulation in radish leaves/vegetables. The USDA Nutrient Database for radish (0.69 μg/g of Mn) contradicts this notion as one would need to consume ~ 7 to 18 lb/day of radish to satisfy their daily intake. This study complements investigations showing that fertilizers induce minimal uptake of heavy metals in food; simultaneously, the net loss of Mn amounts observed in some samples of radish leaves and vegetables is analogous to the dilution effect of minerals/nutrients in edibles. Although a deficiency/excess of Mn in one's diet may lead to adverse health effects, background inhalation exposure in general public, occupational, and emergency response settings has a greater influence on one's propensity toward developing adverse health effects related to Mn inhalation exposure.



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Striking study finds a climate tipping point in clouds

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From ARS Technica We aren't likely to see it happen, but it's still sobering. Scott K. Johnson – 2/25/2019, 6:13 PM Stratocumulus clouds, like those in the lower two-thirds of this image, are common over the oceans. NASA Earth Observatory The word "hysteresis" doesn't immediately seem threatening; it hints at a portmanteau of "history" and…

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A Stable Filamentous Coaxial Microelectrode for Li-ion Batteries: A Case of Olivine LiFePO4

Chem. Commun., 2019, Accepted Manuscript
DOI: 10.1039/C9CC00526A, Communication
Xiaolong Guo, Tu Lan, Liang Zhang, Jingwei Tan, Xiang Feng, De Li, Yong Chen
By using a facile spray drying method, we fabricated a stable filamentous coaxial microelectrode of olivine LiFePO4, which delivers an excellent electrochemical performance in Li-ion batteries. Due to its simple...
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Quick! Tell the PM: Pumped Hydro is not a “generator”. It’s a $2 – $4b energy chewing “renewables” bandaid.

No more excuses for sloppy, inaccurate language. How can you run a country with falsehoods?

Hydropower is a generator. Pumped Hydro is giant appliance that sucks electricity and gives you back some later. In a system with reliable baseload generators it is superfluous, redundant, and entirely unnecessary. It is an expense we don't have to have, didn't need, and don't want to pay for. It can only make things more expensive than the system we used to have. Not only do we have to pay for the giant infrastructure, every day it operates we also throw away 20 – 30% of the electrons (so to speak) that go through it.

Scott Morrison says it's only $1.4 b from the taxpayer, but the total cost may be $4 billion, and as Judith Sloan says, someone's got to pay — if not through taxes, it will be added to electricity prices. The Snowy Corp may "self fund" it (a deceptively nice way to put it), but they won't be donating the money.

And the Snowy Corp couldn't "self-fund" it from electricity bills if they weren't already so ridiculously high.  If we had enough coal power to keep electricity as inexpensive as it [...]

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Schumer pledges to defund Trump’s ‘fake climate panel’

https://ift.tt/2tFobcv By Valerie Richardson – The Washington Times – Updated: 6:42 p.m. on Tuesday, February 26, 2019 Senate Minority Leader Chuck Schumer vowed Tuesday to defund any effort by the Trump administration to form an advisory committee on climate change, calling it a "fake climate panel." His floor remarks came after multiple media outlets reported that the White House […]

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DEAD ON ARRIVAL: DEMOCRATS WON’T BACK ‘GREEN NEW DEAL’ IN ‘SHAM’ VOTE – Would vote ‘present’ to avoid a public intraparty fight

https://ift.tt/2UfKAsB E&E News If Senate Majority Leader Mitch McConnell (R-Ky.) calls a vote on the "Green New Deal," it looks likely that many — or even all — Senate Democrats would vote "present" to avoid a public intraparty fight, said activists, lawmakers and congressional aides. The environmental group behind the climate resolution is not planning […]

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Morano to testify on Capitol Hill – Warmists Outraged – Accuse GOP of stacking Congressional Green New Deal forum with ‘prominent climate deniers’

https://ift.tt/2tGmxah GOP stacks Green New Deal forum with climate deniers and industry groups The Republican-dominated Congressional Western Caucus is hosting a forum on the Green New Deal on Wednesday. The confirmed guests are mostly prominent climate-change deniers and industry-linked groups. "It's clear to any thinking person that this isn't a serious forum," says Demond Drummer, […]

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Evidence that humans are responsible for global warming hits ‘gold standard’ certainty level

An article from Apple news notes: OSLO – Evidence for man-made global warming has reached a "gold standard" level of certainty, adding pressure for cuts in greenhouse gases to limit rising temperatures, scientists said on Monday. "Humanity cannot afford to ignore such clear signals," the U.S.-led team wrote in the journal Nature Climate Change of…

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Corporate Honesty and Climate Change: Time to Own Up and Act

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Vertical variation of bulk and metabolically active prokaryotic community in sediment of a hypereutrophic freshwater lake

Abstract

This study was conducted to acquire novel insight into differences between bulk (16S rDNA) and metabolically active (16S rRNA) prokaryotic communities in the sediment of a hypereutrophic lake (Japan). In the bulk communities, the class Deltaproteobacteria and the order Methanomicrobiales were dominant among bacteria and methanogens. In the metabolically active communities, the class Alphaproteobacteria and the order Methanomicrobiales and the family Methanosaetaceae were frequently found among bacteria and methanogens. Unlike the bulk communities of prokaryotes, the composition of the metabolically active communities varied remarkably vertically, and their diversities greatly decreased in the lower 20 cm of sediment. The metabolically active prokaryotic community in the sediment core was divided into three sections based on their similarity: 0–6 cm (section 1), 9–18 cm (section 2), and 21–42 cm (section 3). This sectional distribution was consistent with the vertical pattern of the sedimentary stable carbon and nitrogen isotope ratios and oxidation–reduction potential in the porewater. These results suggest that vertical disturbance of the sediment may influence the communities and functions of metabolically active prokaryotes in freshwater lake sediments. Overall, our results indicate that rRNA analysis may be more effective than rDNA analysis for evaluation of relationships between actual microbial processes and material cycling in lake sediments.



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[ASAP] Regioselective Hydrogenation of a 60-Carbon Nanographene Molecule toward a Circumbiphenyl Core

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Journal of the American Chemical Society
DOI: 10.1021/jacs.9b00384
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[ASAP] Porosity Dependence of Compression and Lattice Rigidity in Metal–Organic Framework Series

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Journal of the American Chemical Society
DOI: 10.1021/jacs.8b13009
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[ASAP] Titanium-Based Nanoscale Metal–Organic Framework for Type I Photodynamic Therapy

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Journal of the American Chemical Society
DOI: 10.1021/jacs.8b13804
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[ASAP] Spatially Selective and Density-Controlled Activation of Interfacial Mechanophores

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Journal of the American Chemical Society
DOI: 10.1021/jacs.8b10257
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[ASAP] Drastically Reduced Ion Mobility in a Nanopore Due to Enhanced Pairing and Collisions between Dehydrated Ions

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Journal of the American Chemical Society
DOI: 10.1021/jacs.8b08488
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[ASAP] Self-Assembling Micelles Based on an Intrinsically Disordered Protein Domain

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Journal of the American Chemical Society
DOI: 10.1021/jacs.8b10688
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[ASAP] Correction to “Intrinsic Reactivity of Diatomic 3d Transition-Metal Carbides in the Thermal Activation of Methane: Striking Electronic Structure Effects”

Journal of the American Chemical Society
DOI: 10.1021/jacs.9b01919
jacsat?d=yIl2AUoC8zA


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[ASAP] Solution NMR Analysis of Ligand Environment in Quaternary Ammonium-Terminated Self-Assembled Monolayers on Gold Nanoparticles: The Effect of Surface Curvature and Ligand Structure

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Journal of the American Chemical Society
DOI: 10.1021/jacs.8b11445
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[ASAP] Pickering Emulsion-Derived Liquid–Solid Hybrid Catalyst for Bridging Homogeneous and Heterogeneous Catalysis

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Journal of the American Chemical Society
DOI: 10.1021/jacs.8b11860
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[ASAP] Substrate-Driven Transient Self-Assembly and Spontaneous Disassembly Directed by Chemical Reaction with Product Release

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Journal of the American Chemical Society
DOI: 10.1021/jacs.8b12777
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[ASAP] Correction to “Graphene Nanoribbons Derived from Zigzag Edge-Encased Poly(-2,9-dibenzo[,]coronenylene) Polymer Chains”

Journal of the American Chemical Society
DOI: 10.1021/jacs.9b01965
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[ASAP] Directed Functionalization Tailors the Polarized Emission and Waveguiding Properties of Anthracene-Based Molecular Crystals

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Chemistry of Materials
DOI: 10.1021/acs.chemmater.8b05361
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[ASAP] Chemical Stabilities of the Lowest Triplet State in Aryl Sulfones and Aryl Phosphine Oxides Relevant to OLED Applications

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Chemistry of Materials
DOI: 10.1021/acs.chemmater.8b04235
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[ASAP] Versatile Triblock Janus Nanoparticles: Synthesis and Self-Assembly

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Chemistry of Materials
DOI: 10.1021/acs.chemmater.8b05073
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[ASAP] Correction to Toward High-Efficient Red Emissive Carbon Dots: Facile Preparation, Unique Properties, and Applications as Multifunctional Theranostic Agents

Chemistry of Materials
DOI: 10.1021/acs.chemmater.9b00755
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FERC Can't Just Check the Climate Box

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[ASAP] Ultrafast Monolayer In/Gr-WS2-Gr Hybrid Photodetectors with High Gain

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ACS Nano
DOI: 10.1021/acsnano.8b09032
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