Monday, February 4, 2019

A mixed molecular salt of lithium and sodium breaks the Hume-Rothery rules for solid solutions

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Chem. Commun., 2019, Advance Article
DOI: 10.1039/C8CC09850F, Communication
Open Access Open Access
Monica Lestari, Matteo Lusi
Despite the difference in size and chemistry, lithium and sodium form a solid solution as isoorotate salt. Such behaviour, which represents an exception to the Hume-Rothery rules, can be exploited in the preparation of novel lithium drugs.
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