Wednesday, January 16, 2019

Highly Crystalline Ramsdellite as a Cathode Material for Near-Neutral Aqueous MnO2/Zn Batteries

Chem. Commun., 2019, Accepted Manuscript
DOI: 10.1039/C8CC07805J, Communication
Ivan Stosevski, Arman Bonakdarpour, Faye Cuadra, David P Wilkinson
Chemically-prepared MnO2 containing a highly crystalline ramsdellite phase was tested as a cathode material in aqueous Zn-salt (ZnSO4 and Zn(CF3SO3)2) based electrolytes for the first time. This aqueous MnO2/Zn cell...
The content of this RSS Feed (c) The Royal Society of Chemistry


from Journals via hj on Inoreader https://rsc.li/2QSD6Jl

Fake science on fake fish from James Cook Uni?

Third World Science with First World Funding

Is James Cook University a grants machine or a research institute?

James Cook University reviews ex-student's 'fishy' findings, by Graham Lloyd, The Australian

Oona Lonnstedt has been prolific, writing alarming papers on microplastics, acidification, and reef degradation. But her work is starting to look like a trainwreck. One paper has been withdrawn, in another it was "found that Lonnstedt did not have time to undertake the research she claimed." Now Peter Ridd has pointed out that the photos of 50 Lionfish appear to contain a lot less than 50 fish. Images have been flipped, spun or "manipulated" so the same fish appears more than once. This sort of thing is not just "confirmation bias".

James Cook has done what any ambitious, money-hungry grant troughing institute would do, a very slow investigation of allegedly corrupt behaviour and a very quick sacking of the honest researcher who threatens to expose them. Any respectable Science Minister would freeze all grants to James Cook until this situation was resolved and reversed.

Send your thoughts to The Hon Karen Andrews. Contact her here: karen.andrews.mp AT aph.gov.au. There is a crisis in Australian science. Who is going [...]

gfx.php?value=0.0
Rating: 0.0/10 (0 votes cast)



from Climate Change Skeptic Blogs via hj on Inoreader http://bit.ly/2CrGntP

Don’t ban plastic bags!

clip_image002-5.jpg?is-pending-load=1

Learn the facts about plastic versus paper bags – and bag the bans, instead Hal Shurtlef Like dozen towns and cities in Massachusetts and other states, Boston recently enacted a ban on plastic shopping bags. It went into effect December 14, 2018. It was a relatively easy vote, because "evil" plastic bags have received extensive…

from Climate Change Skeptic Blogs via hj on Inoreader http://bit.ly/2Hi3htz

Controlled Ni-catalyzed mono-and double-decarbonylations of α-ketothioesters

Chem. Commun., 2019, Accepted Manuscript
DOI: 10.1039/C8CC09352K, Communication
Zhao-Jing Zheng, Cheng Jiang, Peng-Cheng Shao, Wen-Fei Liu, Tian-Tian Zhao, PengFei Xu, Hao Wei
A method for Ni-catalyzed controlled decarbonylation of α-ketothioesters is described. Mono- and double-decarbonylations, which gave could thioesters and thioethers, respectively, were selectively achieved by changing the ligands. A fundamental study...
The content of this RSS Feed (c) The Royal Society of Chemistry


from Journals via hj on Inoreader https://rsc.li/2QTWV2N

Media Reports of +40% Adjustment in Ocean Warming Were Greatly Exaggerated

Holmes-meme-550x309.jpg?is-pending-load=

From Dr Roy Spencer's Blog January 16th, 2019 Summary: The recently reported upward adjustment in the 1971-2010 Ocean Heat Content (OHC) increase compared to the last official estimate from the IPCC is actually 11%, not 40%. The 40% increase turns out to be relative to the average of various OHC estimates the IPCC addressed in…

from Climate Change Skeptic Blogs via hj on Inoreader http://bit.ly/2CsRKBI

[ASAP] Structural, Chemical, Electrical, and Thermal Properties of -Type NbFeSb

TOC Graphic

Inorganic Chemistry
DOI: 10.1021/acs.inorgchem.8b02531
inocaj?d=yIl2AUoC8zA


from Journals via hj on Inoreader http://bit.ly/2VXFZMH

[ASAP] Optoelectronic Properties of TiS2: A Never Ended Story Tackled by Density Functional Theory and Many-Body Methods

TOC Graphic

Inorganic Chemistry
DOI: 10.1021/acs.inorgchem.8b02883
inocaj?d=yIl2AUoC8zA


from Journals via hj on Inoreader http://bit.ly/2QVnGnA

[ASAP] A Combination of Tri-Leucine and Angiopep-2 Drives a Polyanionic Polymalic Acid Nanodrug Platform Across the Blood–Brain Barrier

TOC Graphic

ACS Nano
DOI: 10.1021/acsnano.8b06437
ancac3?d=yIl2AUoC8zA


from Journals via hj on Inoreader http://bit.ly/2FvTL4m

[ASAP] Catalyst Preoxidation and EDTA Electrolyte Additive Remedy Activity and Selectivity Declines During Electrochemical CO2 Reduction

TOC Graphic

The Journal of Physical Chemistry C
DOI: 10.1021/acs.jpcc.8b08794
jpccck?d=yIl2AUoC8zA


from Journals via hj on Inoreader http://bit.ly/2FFdlKs

[ASAP] Size-Dependent Adsorption of Styrene on Pd Clusters: A Density Functional Theory Study

TOC Graphic

The Journal of Physical Chemistry C
DOI: 10.1021/acs.jpcc.8b09477
jpccck?d=yIl2AUoC8zA


from Journals via hj on Inoreader http://bit.ly/2FxIAI9

[ASAP] Optical Activity and Circular Dichroism of Perovskite Quantum-Dot Molecules

TOC Graphic

The Journal of Physical Chemistry C
DOI: 10.1021/acs.jpcc.8b12041
jpccck?d=yIl2AUoC8zA


from Journals via hj on Inoreader http://bit.ly/2FEzaKo

Elucidating the dechlorination mechanism of hexachloroethane by Pd-doped zerovalent iron microparticles in dissolved lactic acid polymers using chromatography and indirect monitoring of iron corrosion

Abstract

The degradation mechanism of the pollutant hexachloroethane (HCA) by a suspension of Pd-doped zerovalent iron microparticles (Pd-mZVI) in dissolved lactic acid polymers and oligomers (referred to as PLA) was investigated using gas chromatography and the indirect monitoring of iron corrosion by continuous measurements of pH, oxidation-reduction potential (ORP), and conductivity. The first experiments took place in the absence of HCA, to understand the evolution of the Pd-mZVI/PLA/H2O system. This showed that the evolution of pH, ORP, and conductivity is related to changes in solution chemistry due to iron corrosion and that the system is initially cathodically controlled by H+ mass transport to Pd surfaces because of the presence of an extensive PLA layer. We then investigated the effects of Pd-mZVI particles, temperature, initial HCA concentration, and PLA content on the Pd-mZVI/PLA/HCA/H2O system, to obtain a better understanding of the degradation mechanism. In all cases, HCA dechlorination first requires the production of atomic hydrogen H*—involving the accumulation of tetrachloroethylene (PCE) as an intermediate—before its subsequent reduction to non-chlorinated C2 and C4 compounds. The ratio between Pd-mZVI dosage, initial HCA concentration, and PLA content affects the rate of H* generation as well as the rate-determining step of the process. A pseudo-first-order equation can be applied when Pd-mZVI dosage is much higher than the theoretical stoichiometry (600 mg for [HCA]0 = 5–20 mg L−1). Our results indicate that the HCA degradation mechanism includes mass transfer, sorption, surface reaction with H*, and desorption of the product.



from Climate Change Skeptic Blogs via hj on Inoreader http://bit.ly/2VY2JMF

Chloroplast proteomic analysis of Triticum aestivum L. seedlings responses to low levels of UV-B stress reveals novel molecular mechanism associated with UV-B tolerance

Abstract

In this study, we have investigated UV-B-induced alterations including chloroplast ultrastructure, chlorophyll fluorescence parameters, physiological metabolism, and chloroplast proteome profile. Comparison of seedling phenotypic characterization and physiological status revealed that the low level of 1.08 KJ m−2 of UV-B irradiation had no obvious effects on seedling phenotype and growth and maintained better chloroplast ultrastructure and higher photosynthetic efficiency. Nevertheless, the high dose of 12.6 KJ m−2 of UV-B stress caused significant inhibitory effects on the growth and development of wheat seedlings. Proteomic analysis of chloroplasts with or without 1.08 KJ m−2 of UV-B irradiation identified 50 differentially expressed protein spots, of which 35 were further analyzed by MALDI-TOF/TOF mass spectrometry. These proteins were found to be involved in multiple cellular metabolic processes including ATP synthesis, light reaction, Calvin cycle, detoxifying and antioxidant reactions, protein metabolism, malate and tetrapyrrole biosynthesis, and signal transduction pathway. We also identified 3 novel UV-B-responsive proteins, spots 8801, 8802, and 9201, and predicted three new proteins might be UV-B protective proteins. Our results imply chloroplasts play a central protective role in UV-B resistance of wheat seedlings and also provide novel evidences that UV-B stress directly affects on the structure and function of chloroplasts and explore molecular mechanisms associated with plant UV-B tolerance from chloroplast perspective.



from Climate Change Skeptic Blogs via hj on Inoreader http://bit.ly/2QQxgIl

Claim: Global warming causes colder winters and more snow in Europe

From the "with models, we can make anything believable" department. New paper argues for a stronger influence of Arctic sea-ice loss on recent Eurasian cooling, thus causing colder winters and more snow in Europe due to climate change. A reconciled estimate of the influence of Arctic sea-ice loss on recent Eurasian cooling https://go.nature.com/2CjJhRl (paywalled) Abstract…

from Climate Change Skeptic Blogs via hj on Inoreader http://bit.ly/2sxEN5m

Hump day hilarity – the progression of climate narrative names

climate-narrative-names-720x432.png

I had a predictable and laughable Twitter dialog today with the editor of the bought and paid for climate activist site known as "The Carbon Brief". He was bent out of shape because I pointed out that while he thought the reason for the stepping down of Lord Lawson at The Global Warming Policy Foundation…

from Climate Change Skeptic Blogs via hj on Inoreader http://bit.ly/2MltPJn

Our Oceans’ Last Chance: Protect the High Seas



from Climate Change Skeptic Blogs via hj on Inoreader https://on.nrdc.org/2RvfJe2

Tweedledee Or Tweedledum–The Riddle Of Antarctic Ice Melt

By Paul Homewood

 

Antarctica is losing ice at an alarming rate six times greater than in 1979 thanks to climate change. Sea levels rose by more than half an inch since the study started in 1979 and scientists expect 'multi-meter' loss of ice n the upcoming centuries (stock image) 

Is the Antarctic gaining or losing ice?

Yesterday I took a look at the latest NASA study claiming that the Antarctic has been losing ice since 1992, in stark contrast to another NASA study in 2015, which claimed the opposite.

The new study comes from the ice sheet mass balance inter-comparison exercise, IMBIE, which has a totally different methodology than the 2015 research by Jay Zwally.

The volume of the ice cap depends essentially on two elements:

1) Surface Mass Balance (SMB), which is increased by snowfall and reduced by melt or evaporation

2) Drainage, either where the ice flows away to melt, or is calved.

The Zwally study attempted calculate how much the ice sheet is growing or shrinking from the changes in surface height that are measured by the satellite altimeters.

IMBIE however use a different approach to measuring SMB. Rather than attempting to measure surface height, they rely on atmospheric models to guesstimate the amount of snowfall, assuming that sublimation and meltwater is relatively insignificant.

There are, of course, huge uncertainties about both approaches.

As another NASA study by Medley & Thomas last month noted:

Snowfall is very difficult to measure over Antarctica. For starters, there are very few weather stations in the frozen continent, and most of them are installed along the coastline. Secondly, satellites have a hard time measuring snow from space – they basically confuse the snow that's falling down with the snow that's already on the ground. Climate models struggle to replicate the total amount of snow that falls over Antarctica each year. So scientists often have to rely on ice cores, cylinders of ice drilled from the ice sheet whose layers store a trove of information; amongst it, how much snow fell in a certain year or decade. But drilling ice cores is logistically challenging, so they are sparse and do not cover the entire continent.

https://www.nasa.gov/feature/goddard/2018/snow-over-antarctica-buffered-sea-level-rise-during-last-century

This study instead used ice cores, and concluded that snowfall had slightly increased during the 20thC, something that would logically follow from a warmer climate.

 

But whether you use ice cores, climate models or weather stations, the results will be subject to massive uncertainty. Indeed, many would argue the results are worthless statistically.

Zwally's satellite approach has its own drawbacks as well, not least the problem of allowing for Glacial Isostatic Adjustment. This is to compensate for the fact that the land is rising where glaciers are melting, and sinking where ice mass accumulates.

 

Which approach is better, I have no idea. But what is clear is that calculations of snowfall are absolutely critical to the final equation, as snowfall is such a significant contributor.

According to IMBIE, net accumulation of ice (ie snowfall minus evaporation/meltwater) is 1994 Gt/yr. Yet their claimed net ice loss over Antarctica between 1992 and 2017 is only 2720 Gt, which equals 109 Gt pa .

In other words, their estimated ice loss is only 5% of the net accumulation. If that estimate is 5% too low, then Antarctica has gained ice, and not lost it.

The claimed error margin over 1992 to 2018 is 1390 Gt. But this is simply made up. Statistically speaking, to estimate a margin of error you rely on the pool of data you have got. But as we have seen, this pool of data is virtually non existent.

The true margin of error in Antarctica should reflect the lack of data, and not the variability of the tiny amount of data which you do have.

 

As I stated yesterday, nobody has the slightest idea what is happening to the ice mass in the Antarctic, even to the extent of whether or not it is increasing or decreasing.

In most disciplines, these sort of studies would be regarded as junk science – useful for comparing different approaches, but meaningless as far as results are concerned. Unfortunately the normal rules don't apply to climate science, where money rules.

 

As I also mentioned, the best method we have of estimating these sort of things is tidal gauges, which can give us accurate measures of relative sea level changes over a period of time.

Consistently, wherever we look around the world, we find that the current rate of rise has changed little in comparison with the mid 20thC.

If Antarctic ice melt really was accelerating, this could only mean that other factors were causing sea level rise to slow, such as Greenland ice melt, other glaciers, or thermal expansion.

Either way, there is nothing in the tidal gauge record to support alarmist projections of rapidly rising seas.



from Climate Change Skeptic Blogs via hj on Inoreader http://bit.ly/2RvajzI

Enhanced electrochemical performance and high voltage window for supercapacitor based on multi-heteroatom modified porous carbon materials

GA?id=C8CC08391F

Chem. Commun., 2019, Advance Article
DOI: 10.1039/C8CC08391F, Communication
Yalei Deng, Yajun Ji, Hongmei Wu, Fei Chen
Enhanced electrochemical performance and high voltage window for supercapacitor based on the multi-heteroatom modified porous carbon materials.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


from Journals via hj on Inoreader https://rsc.li/2FEaJwK

High Seas: Few Rules, Fewer Sheriffs

oceancombo1_2400.jpg?itok=uMcAnJ-_



from Climate Change Skeptic Blogs via hj on Inoreader https://on.nrdc.org/2DeYKE2

Electric Cars 101



from Climate Change Skeptic Blogs via hj on Inoreader https://on.nrdc.org/2CqT6gl

[ASAP] Crystalline Ammonium Peroxogermanate as a Waste-Free, Fully Recyclable Versatile Precursor for Germanium Compounds

TOC Graphic

Inorganic Chemistry
DOI: 10.1021/acs.inorgchem.8b02747
inocaj?d=yIl2AUoC8zA


from Journals via hj on Inoreader http://bit.ly/2sv30cl

[ASAP] Computational Mechanistic Study of [MoFe3S4] Cubanes for Catalytic Reduction of Nitrogenase Substrates

TOC Graphic

Inorganic Chemistry
DOI: 10.1021/acs.inorgchem.8b02669
inocaj?d=yIl2AUoC8zA


from Journals via hj on Inoreader http://bit.ly/2syllFi

[ASAP] Synthesis and Catalytic Properties of Dirhodium Paddlewheel Complexes with Tethered, Axially Coordinating Thioether Ligands

TOC Graphic

Inorganic Chemistry
DOI: 10.1021/acs.inorgchem.8b02627
inocaj?d=yIl2AUoC8zA


from Journals via hj on Inoreader http://bit.ly/2suh3Pg

[ASAP] Nanosheets of Nickel Iron Hydroxy Carbonate Hydrate with Pronounced OER Activity under Alkaline and Near-Neutral Conditions

TOC Graphic

Inorganic Chemistry
DOI: 10.1021/acs.inorgchem.8b02680
inocaj?d=yIl2AUoC8zA


from Journals via hj on Inoreader http://bit.ly/2sx7zCW

[ASAP] Hydrolysis of 2D Transition-Metal Carbides (MXenes) in Colloidal Solutions

TOC Graphic

Inorganic Chemistry
DOI: 10.1021/acs.inorgchem.8b02890
inocaj?d=yIl2AUoC8zA


from Journals via hj on Inoreader http://bit.ly/2suQYQ8

Origin and behavior of radionuclides in sediment core: a case study of the sediments collected from man-made reservoirs located in the past mining region in Central Slovakia

Abstract

The analyzed sediments were taken from the man-made reservoirs (Velka Richnava, Rozgrund and Vindsachta) located in an area intensively mined for polymetallic ores since the end of the eleventh century (Banska Stiavnica region, Central Europe). The aims of this study were to determine the radioactivity of natural (226Ra, 228Th, 210Pb) and artificial (137Cs and 241Am) radionuclides, compare the radionuclides' distribution, and indicate the correlation of radioisotopes and their origin related to sediment properties. Two analytical techniques were used. 228Th, 226Ra, 241Am, and 137Cs were measured by means of gamma spectrometry and 210Pb was determined by its daughter radionuclide 210Po using alpha spectrometry. The results showed that the highest mean level of 226Ra (42.6 Bq·kg−1), 228Th (49.7 Bq·kg−1) and 210Pb (75.2 Bq·kg−1) was in the sediments collected from Rozgrund. The radioactivity of 137Cs and 241Am were present at a higher level in the layer related to Chernobyl (1986) accident and nuclear weapon test (1950/1960). The distribution of natural radionuclides was quite similar in all reservoirs. Chemometric analysis confirmed the radionuclides' origin and correlation between the analyzed parameters.



from Climate Change Skeptic Blogs via hj on Inoreader http://bit.ly/2sqKySi

[ASAP] Assessing Correlations of Perovskite Catalytic Performance with Electronic Structure Descriptors

TOC Graphic

Chemistry of Materials
DOI: 10.1021/acs.chemmater.8b03840
cmatex?d=yIl2AUoC8zA


from Journals via hj on Inoreader http://bit.ly/2st6Gvf

[ASAP] Trimethylsilyl Iodine-Mediated Synthesis of Highly Bright Red-Emitting CsPbI3 Perovskite Quantum Dots with Significantly Improved Stability

TOC Graphic

Chemistry of Materials
DOI: 10.1021/acs.chemmater.8b04049
cmatex?d=yIl2AUoC8zA


from Journals via hj on Inoreader http://bit.ly/2MiZ0oE

[ASAP] Controlling Dimensionality in the Ni–Bi System with Pressure

TOC Graphic

Chemistry of Materials
DOI: 10.1021/acs.chemmater.8b04412
cmatex?d=yIl2AUoC8zA


from Journals via hj on Inoreader http://bit.ly/2sx7hfk

Collaboration request

Hi there How would you like to earn a 35% commission for each sale for life by selling SEO services Every website owner requires the ...