Tuesday, January 8, 2019

Synthesis of carbonyl-bridged dibenzofulvalenes and related compounds by rhodium-catalyzed stitching reaction

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Chem. Commun., 2019, Advance Article
DOI: 10.1039/C8CC09943J, Communication
Ryo Shintani, Shinnosuke Kishikawa, Kimihiro Nakamura, Tomohiro Tsuda, Kyoko Nozaki
Various carbonyl-bridged dibenzofulvalenes were synthesized by a sequence of rhodium-catalyzed stitching reaction and post-functionalization, and other bridged dibenzofulvalenes could also be synthesized using the present stitching reaction.
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