Tuesday, January 8, 2019

Rhodium(III)-catalyzed regioselective oxidative annulation of anilines and allylbenzenes via C(sp3)–H/C(sp2)–H bond cleavage

GA?id=C8CC09099H

Chem. Commun., 2019, Advance Article
DOI: 10.1039/C8CC09099H, Communication
Yunqi Liu, Yudong Yang, Chunxia Wang, Zhishuo Wang, Jingsong You
As a proof-of-concept, we disclose the rhodium-catalyzed oxidative annulation of anilines with allylbenzenes to afford a variety of indoles, in which the allylic C(sp3)–H activation and directed C(sp2)–H activation are merged into a single approach for the first time.
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