Tuesday, January 8, 2019

Difluorocarbene-derived trifluoromethylselenolation of benzyl halides

Chem. Commun., 2019, Accepted Manuscript
DOI: 10.1039/C8CC09719D, Communication
Xin-Lei Chen, Sheng-Hua Zhou, Jin-Hong Lin, Qing-Hai Deng, Ji-Chang Xiao
Cu-promoted difluorocarbene-derived trifluoromethylselenolation of benzyl halides with the Ph3P+CF2CO2-/Se/F- system is described. Three new carbon−heteroatom bonds, Se-CF2 bond, SeCF2-F bond, and C-SeCF3 bond, were sequentially formed in the reaction. This...
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