Tuesday, January 8, 2019

Dimanganese(III) porphyrin dication diradical and its transformation to a μ-hydroxo porphyrin-oxophlorin heterodimer

Chem. Commun., 2019, Accepted Manuscript
DOI: 10.1039/C8CC09366K, Communication
Amit Kumar, Debangsu Sil, Mohammad Usman, Sankar Prasad Rath
We investigate here the effect of electronic communication between two Mn(III) porphyrin π-cation radicals, connected covalently through an ethylene bridge, which exhibited significant electronic communication resulting in strong antiferromagnetic coupling...
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