Friday, January 25, 2019

Synthesis of 9-Borafluorene Analogues Featuring a Three-Dimensional 1,1’-Bis(o-carborane) Backbone

Chem. Commun., 2019, Accepted Manuscript
DOI: 10.1039/C8CC10087J, Communication
Sam Yruegas, Jonathan Axtell, Kent Kirlikovali, Alex Spokoyny, Caleb Daniel Martin
The synthesis of [1,1'-bis(o-carboranyl)]boranes was achieved through the deprotonation of 1,1'-bis(o-carborane) reagents followed by salt metathesis with (iPr)2NBCl2. X-ray crystallography confirms planar central BC4 rings and Gutmann-Beckett studies reveal an...
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