Friday, January 25, 2019

(PhC(NtBu)2Al)2(SiH2)4 Six-Membered Heterocycle: Comparable in Structure to Cyclohexane

Chem. Commun., 2019, Accepted Manuscript
DOI: 10.1039/C8CC10124H, Communication
Open Access Open Access
Herbert W Roesky, Jiancheng Li, Zhong Mingdong, Helena Keil, Hongping Zhu, Regine Herbst-Irmer, Dietmar Stalke, Debasis Koley, Sriman De
A silicon-aluminum heterocycle LAl(SiH2SiH2)2AlL (L = PhC(NtBu)2) (1) was prepared. Compound 1 exhibits a unique (N2Al)2(SiH2)4 centrosymmetric six-membered ring structure with chair conformation, which is comparable with that of cyclohexane....
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