Solvent-assisted synthesis of shape-persistent chiral polyaza gigantocycle characterized by a very large internal cavity and extraordinarily high amplitude of the ECD exciton couplet

Chem. Commun., 2019, Accepted Manuscript
DOI: 10.1039/C8CC10184A, Communication

Mikołaj Zgorzelak, Jakub Grajewski, Jacek Gawronski, Marcin Kwit
A giant, chiral square-shaped octaimine macrocycle has been obtained in a controlled manner from readily available and inexpensive substrates: 9,10-diphenylanthracene-based dialdehyde and trans-1,2-diaminocyclohexane. Reduction of the polyimine led to chiral...
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