Monday, February 18, 2019

Conversion of dinitrogen to tris(trimethylsilyl)amine catalyzed by titanium triamido-amine complexes

Chem. Commun., 2019, Accepted Manuscript
DOI: 10.1039/C8CC09742A, Communication
Jun Okuda, Thomas Paul Spaniol, Paul Kögerler, Priyabrata Ghana, Franziska D. van Kruechten, Jan van Leusen
By using a triaryl-Tren ligated titanium dinitrogen complex, K2[(Xy-N3N)Ti2(µ2-N2)] (3), prepared by two-electron reduction of [TiCl(Xy-N3N)] (1-Cl) under N2 atmosphere, catalytic fixation of molecular nitrogen to form tris(trimethylsilyl)amine was achieved...
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