Thursday, January 3, 2019

Silyl–pyridine–amine pincer-ligated iridium complexes for catalytic silane deuteration via room temperature C–D bond activation of benzene-d6

GA?id=C8CC09178A

Chem. Commun., 2019, Advance Article
DOI: 10.1039/C8CC09178A, Communication
Takashi Komuro, Tomohiro Osawa, Ryuju Suzuki, Daiki Mochizuki, Hironori Higashi, Hiromi Tobita
SiNN-pincer iridium complexes were synthesised and demonstrated to catalyse deuteration of trialkylsilanes with benzene-d6 through H/D exchange at room temperature.
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