Friday, January 4, 2019

Light-mediated copper-catalyzed phosphorus/halogen exchange in 1,1-difluoroalkylphosphonium salts

Chem. Commun., 2019, Accepted Manuscript
DOI: 10.1039/C8CC09115C, Communication
Liubov I. Panferova, Vitalij V. Levin, Marina Struchkova, Alexander Dilman
A method for the assembling of the halodifluoromethyl group (CF2X, X = Cl, Br, I) is described. The reaction involves the light-mediated substitution of the triphenylphosphine by halide anions in...
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