Friday, January 4, 2019

Enantioselective iridium-catalyzed carbonyl isoprenylation via alcohol-mediated hydrogen transfer

GA?id=C8CC09706B

Chem. Commun., 2019, Advance Article
DOI: 10.1039/C8CC09706B, Communication
Ming Xiang, Guoshun Luo, Yuankai Wang, Michael J. Krische
Enantioselective carbonyl isoprenylation is achieved via alcohol-mediated hydrogen transfer, enabling asymmetric total syntheses of the terpenoid natural products (+)-ipsenol and (+)-ipsdienol.
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