Monday, January 7, 2019

A Self-Hydrosilylation of Phosphanylhydrosilylalkynes Promoted by B(C6F5)3? An Experimental and Mechanistic Study

Chem. Commun., 2019, Accepted Manuscript
DOI: 10.1039/C8CC09022J, Communication
Hongping Zhu, Yanting Huang, Xiaoping Wang, Yan Li, Ming-Chung Yang, Ming-Der Su
Phosphanylhydrosilylalkynes Me2HSiC≡CPAr2 (Ar = Ph, 1a; 4-MeC6H4, 1b) were synthesized, which reacted with B(C6F5)3 to produce alkenes [(E)-(C6F5)3BCH=C(PAr2)SiMe2]2 (2a and 2b) and (Z)-(C6F5)2BCH=C(PAr2)SiMe2(C6F5) (3a and 3b). The formation of 2a...
The content of this RSS Feed (c) The Royal Society of Chemistry


from Journals via hj on Inoreader https://rsc.li/2SGHHjJ

No comments:

Post a Comment

Collaboration request

Hi there How would you like to earn a 35% commission for each sale for life by selling SEO services Every website owner requires the ...