A nucleophilic gold complex
A nucleophilic gold complex, Published online: 21 January 2019; doi:10.1038/s41557-018-0198-1
A two-coordinate monovalent gold complex that features a highly polarized aluminium–gold covalent bond, Alδ+–Auδ−, has been synthesized using a very strongly electron-donating aluminyl ligand. In solution, the complex reacts as a nucleophilic source of gold towards heteroallenes such as carbodiimides and CO2.from Journals via hj on Inoreader https://go.nature.com/2Dqfico
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