Silylene induced cooperative B–H bond activation and unprecedented aldehyde C–H bond splitting with amidinate ring expansion

Chem. Commun., 2019, Accepted Manuscript
DOI: 10.1039/C9CC00296K, Communication

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Herbert W Roesky, V S. V. S. N. Swamy, Kumar Vanka, K. Vipin Raj, Sakya Singha Sen
The addition of HBpin to PhC(NtBu)2SiN(SiMe3)2 (1) results in the cleavage of the B‒H bond in a cooperative fashion across the Si and amidinate-C sites. The reactions of 1 with...
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