Monday, February 25, 2019

Proton-Coupled Electron Transfer Oxidation of O-H Bond by the N-Radical Cation of Wurster’s Blue Salt (TMPDA•+)

Chem. Commun., 2019, Accepted Manuscript
DOI: 10.1039/C9CC00354A, Communication
Han Li, Yu-Hua Guo, Jun-Yan Wu, Ming-Tian Zhang
Here we report the proton-coupled electron transfer reaction between TEMPO-H and Wurster's Blue salt (TMPDA•+). TMPDA•+ could abstract a hydrogen atom from 2, 2, 6, 6-tetramethyl-1-hydroxy-piperidine (TEMPO-H) via concerted electron-proton...
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