Monday, February 25, 2019

Crystal-to-crystal interconversion of open and closed dicopper(II) paddle-wheels in a heterotrimetallic coordination polymer

Chem. Commun., 2019, Accepted Manuscript
DOI: 10.1039/C9CC00152B, Communication
Hayato Ohwaki, Nobuto Yoshinari, Takumi Konno
Treatment of [Au2Pd(dppm)(D-pen)2] ([1]) with Cu(NO3)2 gave a 1D (AuI2PdIICuII2)n coordination polymer, [Cu2(1)2(H2O)4](NO3)4 ([2](NO3)4), which was reversibly converted to its dehydrated species, [Cu2(1)2(H2O)2](NO3)4 ([3](NO3)4), with retention of crystallinity. The magnetic...
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