Wednesday, January 23, 2019

Mechanochemically directed metathesis in Group 2 chemistry: Calcium amide formation without solvent

Chem. Commun., 2019, Accepted Manuscript
DOI: 10.1039/C8CC10155H, Communication
Isaiah R. Speight, Stephen C. Chmely, Timothy P. Hanusa, Arnold L Rheingold
Ball milling CaI2 and [KN(SiMe3)2] in a 1:1 ratio without solvent, and then extracting the ground material with toluene, yields the synthetically valuable neutral amide [Ca(N(SiMe3)2)2] in good yield, without...
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