Soft-donor dipicolinamide derivatives for selective actinide(III) / lanthanide(III) separation: The role of S- vs. O-donor sites

Chem. Commun., 2019, Accepted Manuscript
DOI: 10.1039/C8CC07683A, Communication

Ingrid Lehman-Andino, Jing Su, Konstantinos E Papathanasiou, Teresa M. Eaton, Jiwen Jian, David Dan, Thomas Albrecht-Schmitt, Christopher Dares, Enrique R Batista, Ping Yang, John K Gibson, Konstantinos Kavallieratos
Selectivity for An(III) vs. Ln(III) binding and extraction using dipicolinamide analogs containing the C=O vs. C=S groups was investigated in solution, gas-phase, and by DFT calculations. The results show higher...
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