Monday, February 11, 2019

Visible-Light Activated Metal Catalyst-Free Vicinal Diazidation of Olefins with Sulfonium Iodate (I) Species

Chem. Commun., 2019, Accepted Manuscript
DOI: 10.1039/C9CC00007K, Communication
Thurpu Raghavender Reddy, Dodla Sivanageswara Rao, Sudhir Kashyap
A visible light-induced vicinal diazidation of various alkenes using stable sulfonium bis(acetoxy)iodate(I) and sodium azide as radical precursor is described. The trimethylsulfonium [bis(azido)iodate(I)] species, intrinsically generated in situ, demonstrated unprecedented...
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