Diphosphination of CO2 and CS2 mediated by frustrated Lewis pairs - catalytic route to phosphanyl derivatives of formic and dithioformic acid

Chem. Commun., 2019, Accepted Manuscript
DOI: 10.1039/C9CC00621D, Communication

Natalia Szynkiewicz, Łukasz Ponikiewski, Rafał Grubba
The first example of CO₂ diphosphination is described. Reactions of unsymmetrical diphosphanes with CE₂ (E = O, S) catalyzed by BPh₃ insert a CE₂ molecule into the P-P bond with...
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