Thursday, February 14, 2019

Unusual ligand rearrangement: from N-phosphinoguanidinato to phosphinimine-amidinato compounds

GA?id=C9CC00432G

Chem. Commun., 2019, Advance Article
DOI: 10.1039/C9CC00432G, Communication
Rafael Fernández-Galán, Alberto Ramos, Estefanía Huergo, Antonio Antiñolo, Fernando Carrillo-Hermosilla, Antonio Rodríguez-Diéguez, Daniel García-Vivó
N,N′-Phosphinoguanidinate Al compounds rearrange under mild conditions to phosphinimine-amidinato derivatives via an unprecedented carbodiimide de-insertion followed by [3+2] cycloaddition.
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