Thursday, February 14, 2019

Cationic Magnesium Hydride [MgH]+ Stabilized by an NNNN-Type Macrocycle

Chem. Commun., 2019, Accepted Manuscript
DOI: 10.1039/C9CC00490D, Communication
Jun Okuda, Lara E. Lemmerz, Debabrata Mukherjee, Thomas Paul Spaniol, Maron Laurent, Gabriel Menard, Anthony Wong
A magnesium hydride cation [(L)MgH]+ supported by a macrocyclic ligand (L = Me4TACD; 1,4,7,10-tetramethyl-1,4,7,10-tetraazacyclo-dodecane) has been prepared by selective protonolysis of a mixed amide hydride [(L)MgH2Mg(N{SiMe3}2)2] and shown to undergo...
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