Wednesday, February 20, 2019

Thiaborane clusters with the exoskeletal B-H group

Chem. Commun., 2019, Accepted Manuscript
DOI: 10.1039/C9CC00952C, Communication
Jan Vrana, Josef Holub, Maksim Andreevich Samsonov, Zdenka Ruzickova, Jindrich Fanfrlik, Drahomír Hnyk, Aleš Růžička
The thiaboranes closo-1-SB11H11 (1a) and 12-I-closo-1-SB11H10 (1b) react with 4-(dimethylamino)pyridine under inert conditions upon the formation of the nido-type thiaboranes 9-B{(4-Me2N)C5NH4}2(H)-7-SB10H11 and 9-B{(4-Me2N)C5NH4}2(H)-5-I-7-SB10H10 containing the exoskeletal B-H group. The same...
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