Wednesday, February 27, 2019

Reversible dielectric switching behavior of a 1D coordination polymer induced by photo and thermal irradiation

Chem. Commun., 2019, Accepted Manuscript
DOI: 10.1039/C9CC00864K, Communication
Jia-Yun SiMa, Hong-Xi Li, david James Young, Pierre Braunstein, Jian-Ping Lang
Solvothermal reaction of Zn(NO3)2 with 2,9-bis-(2-pyridine-3-yl-vinyl)-[1,10]phenanthroline (3-bpep) and furan-2,5-dicarboxylic acid (2,5-H2FDC) afforded a one-dimensional (1D) coordination polymer {[Zn2(3-bpep)2(2,5-FDC)2]•1.5H2O}n (1), which undergoes regioselective photocycloaddition to yield another 1D coordination polymer {[Zn2(3-bpep)(trans,rctt-3-bpbpycb)0.5(2,5-FDC)2]•H2O}n...
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