Monday, January 14, 2019

Unravelling Nucleophilic Aromatic Substitution Pathways with Bimetallic Nucleophiles

Chem. Commun., 2019, Accepted Manuscript
DOI: 10.1039/C8CC09701A, Communication
Martí Garçon, Clare Bakewell, Andrew J P White, Mark Richard Crimmin
The reaction of a metal complex containing a polar Fe–Mg bond with 2-(pentafluorophenyl)pyridine leads to selective C–F bond activation. A stepwise SNAr mechanism involving attack of the bimetallic nucleophile on...
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