Friday, January 18, 2019

Synthesis of free and ligated 1,2-thiaphosphetanes – expanding the pool of strained P-ligands

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Chem. Commun., 2019, Advance Article
DOI: 10.1039/C8CC09892A, Communication
Andreas Wolfgang Kyri, Florian Gleim, David Becker, Gregor Schnakenburg, Arturo Espinosa Ferao, Rainer Streubel
The 1,2-thiaphosphetane heterocycle could be synthesized for the first time in the coordination sphere of a metal complex (I) from which the free ligand (II) could be obtained, too.
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