Friday, January 18, 2019

A cyanide-bridged wheel featuring a seven-coordinate Mo(III) center

Chem. Commun., 2019, Accepted Manuscript
DOI: 10.1039/C8CC09373C, Communication
David Kenneth Kempe, Brian Dolinar, Kuduva R. Vignesh, Toby Woods, Mohamed R Saber, Kim R. Dunbar
A new cyclic molecule incorporating [MoIII(CN)7]4- has been characterized by single crystal X-ray methods, SQUID magnetometry and theoretical calculations. The wheel molecule [MoIII(CN)7]6[Ni(L)]12(H2O)6 exhibits ferromagnetic Mo-Ni coupling which did not...
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