Chem. Commun., 2019, Advance Article
DOI: 10.1039/C8CC09710K, Communication
DOI: 10.1039/C8CC09710K, Communication
Veronica Carta, Miguel A. Soto, Mark J. MacLachlan
An unstrained metal-containing macrocycle was ring-expanded by a ring-opening metathesis strategy, leading to the formation of a bimetallic dimeric macrocycle. The reaction is driven by coordination of a bulky ligand, 2,6-lutidine, on the fourth coordination site of the palladium center. In the absence of metal, or with a less bulky ligand, the ring-expansion reaction does not proceed.
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An unstrained metal-containing macrocycle was ring-expanded by a ring-opening metathesis strategy, leading to the formation of a bimetallic dimeric macrocycle. The reaction is driven by coordination of a bulky ligand, 2,6-lutidine, on the fourth coordination site of the palladium center. In the absence of metal, or with a less bulky ligand, the ring-expansion reaction does not proceed.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry
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