Friday, January 11, 2019

Halogenation of A-Frame μ-Carbido Complexes: Synthesis of η2-Halocarbynes

Chem. Commun., 2019, Accepted Manuscript
DOI: 10.1039/C8CC09692A, Communication
Anthony Hill, Harrison J Barnett
The reaction of [Rh2(μ-C)Cl2(PPh3)4] with bis(diphenylphosphino)methane (dppm) affords the A-frame μ-carbido complex [Rh2(μ-C)Cl2(-dppm)2], halide metathesis of which provides [Rh2(μ-C)Br2(μ-dppm)2]. The reactions of the former with PhICl2 or the latter with...
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