Wednesday, February 6, 2019

Palladium-Catalyzed Double-Bond Migration of Unsaturated Hydrocarbons Accelerated by Tantalum Chloride

Chem. Commun., 2019, Accepted Manuscript
DOI: 10.1039/C9CC00223E, Communication
Masahito Murai, Kengo Nishimura, Kazuhiko Takai
The operationally simple palladium-catalyzed double-bond migration without heteroatom-containing coordinating functional groups is described. Addition of TaCl5 as a second catalyst greatly enhanced the migration efficiency to provide β-alkylstyrenes through migration...
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