Thursday, January 17, 2019

Synthesis of a Dimeric Phosphine-Stabilized Phosphidogermanium(I)-Amidogermanium(II) Derivative

Chem. Commun., 2019, Accepted Manuscript
DOI: 10.1039/C8CC09454C, Communication
Cheuk-Wai So, Muhammad Luthfi Bin Ismail
The synthesis of a dimeric phosphine-stabilized phosphidogermanium(I)-amidogermanium(II) derivative is described. The reaction of the amidinato phosphinoamidosilylene [L{(Ar)(Ph2P)N}Si:] (1, L = PhC(NtBu)2, Ar = 2,6-iPr2C6H3) with GeCl2.dioxane afforded a phosphine-stabilized phosphidogermanium(I)...
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