Chem. Commun., 2019, Accepted Manuscript
DOI: 10.1039/C8CC10122A, Communication
DOI: 10.1039/C8CC10122A, Communication
Sam Greatorex, Kevin B Vincent, Amgalanbaatar Baldansuren, Eric J L McInnes, Nathan John Patmore, Stephen Sproules, Malcolm Halcrow
The catecholate groups in [{Pt(L)}3(μ3-tctq)] (H6tctq = 2,3,6,7,10,11-hexahydroxy-4b,8b,12b,12d-tetramethyltribenzotriquinacene; L = a diphosphine chelate) undergo sequential oxidation to their semiquinonate forms by voltammetry, with ΔE½ = 160–170 mV. The monoradical [{Pt(dppb)}3(μ3-tctq•)]+...
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The catecholate groups in [{Pt(L)}3(μ3-tctq)] (H6tctq = 2,3,6,7,10,11-hexahydroxy-4b,8b,12b,12d-tetramethyltribenzotriquinacene; L = a diphosphine chelate) undergo sequential oxidation to their semiquinonate forms by voltammetry, with ΔE½ = 160–170 mV. The monoradical [{Pt(dppb)}3(μ3-tctq•)]+...
The content of this RSS Feed (c) The Royal Society of Chemistry
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