Wednesday, January 9, 2019

Conversion of Methane to Ethylene Using an Ir Complex and Phosphorus Ylide as a Methylene Transfer Reagent

Chem. Commun., 2019, Accepted Manuscript
DOI: 10.1039/C8CC08761J, Communication
Pavel Zatsepin, Seihwan Ahn, Bimal Pudasaini, Michael Gau, Mu-Hyun Baik, Daniel J Mindiola
Cp*(Me3P)Ir(CH3)(OTf), a complex known to reversibly activate CH4 and other hydrocarbons under mild conditions, reacts with the phosphorus ylide H2CPPh3 in THF to afford two major species [Cp*(Me3P)(Ph3P)Ir(CH2CH3)][OTf] and [Cp*(Me3P)Ir(H)(η2-CH2CH2)][OTf]....
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